2009Pure and Applied ChemistryOpen access

Dispersity in polymer science (IUPAC Recommendations 2009)

R. F. T. Stepto

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Abstract

Abstract This recommendation defines just three terms, viz., (1) molar-mass dispersity, relative-molecular-mass dispersity, or molecular-weight dispersity; (2) degree- of-polymerization dispersity; and (3) dispersity. "Dispersity" is a new word, coined to replace the misleading, but widely used term "polydispersity index" for M w / M n and X w / X n . The document, although brief, also has a broader significance in that it seeks to put the terminology describing dispersions of distributions of properties of polymeric (and non-polymeric) materials on an unambiguous and justifiable footing.

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Abstract This recommendation defines just three terms, viz., (1) molar-mass dispersity, relative-molecular-mass dispersity, or molecular-weight dispersity; (2) degree- of-polymerization dispersity; and (3) dispersity. "Dispersity" is a new word, coined to replace the misleading, but widely used term "polydispersity index" for M w / M n and X w / X n . The document, although brief, also has a broader significance in that it seeks to put the terminology describing dispersions of distributions of properties of polymeric (and non-polymeric) materials on an unambiguous and justifiable footing.

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Available abstract

Abstract This recommendation defines just three terms, viz., (1) molar-mass dispersity, relative-molecular-mass dispersity, or molecular-weight dispersity; (2) degree- of-polymerization dispersity; and (3) dispersity. "Dispersity" is a new word, coined to replace the misleading, but widely used term "polydispersity index" for M w / M n and X w / X n . The document, although brief, also has a broader significance in that it seeks to put the terminology describing dispersions of distributions of properties of polymeric (and non-polymeric) materials on an unambiguous and justifiable footing.

Key concepts: Dispersity, Chemistry, Molar mass, Chemical nomenclature, Polymer, Terminology, Polymerization, Polymer science

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