1983Journal of Wood Chemistry and TechnologyRequires access

Effect of Alkali Fsetreatment Gn Eucalypt Chips on Kraft Black Liqucr Viscosity and Pulp Strength

H. Veeramanl, Matahie BABA, L. N. Chowdhary, U. L. Saksena

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Abstract

Higher viscosity of eucalypt kraft black liquor is apparently caused by a condensation of the poly-phenolic extractives with lignin during pulping. Extraction of the chips with 0.1–0.2 N NaOH at 115–125°c for 4 hours is suggested, prior to pulping, for removing most of the tannin-like material constituting about 1054 of plantation grown eucalypt (E. Tereticornls hybrid, 8–10 years old). Pulp yield. Kappa number and strength of a control cook with 16% active alkali are maintained with 13–14% chemical charge for the extracted chips. Viscosity data for black liquors at 80–100°C for concentrations up to 61% show lower values for extracted chips. The viscosity for 50% black liquor at 100°C decreases by one-third and two-third after pulping chips extracted with 0.l and 0.2 N NaOH, respectively.

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Higher viscosity of eucalypt kraft black liquor is apparently caused by a condensation of the poly-phenolic extractives with lignin during pulping. Extraction of the chips with 0.1–0.2 N NaOH at 115–125°c for 4 hours is suggested, prior to pulping, for removing most of the tannin-like material constituting about 1054 of plantation grown eucalypt (E. Tereticornls hybrid, 8–10 years old). Pulp yield. Kappa number and strength of a control cook with 16% active alkali are maintained with 13–14% chemical charge for the extracted chips. Viscosity data for black liquors at 80–100°C for concentrations up to 61% show lower values for extracted chips. The viscosity for 50% black liquor at 100°C decreases by one-third and two-third after pulping chips extracted with 0.l and 0.2 N NaOH, respectively.

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Available abstract

Higher viscosity of eucalypt kraft black liquor is apparently caused by a condensation of the poly-phenolic extractives with lignin during pulping. Extraction of the chips with 0.1–0.2 N NaOH at 115–125°c for 4 hours is suggested, prior to pulping, for removing most of the tannin-like material constituting about 1054 of plantation grown eucalypt (E. Tereticornls hybrid, 8–10 years old). Pulp yield. Kappa number and strength of a control cook with 16% active alkali are maintained with 13–14% chemical charge for the extracted chips. Viscosity data for black liquors at 80–100°C for concentrations up to 61% show lower values for extracted chips. The viscosity for 50% black liquor at 100°C decreases by one-third and two-third after pulping chips extracted with 0.l and 0.2 N NaOH, respectively.

Key concepts: Kappa number, Soda pulping, Chemistry, Black liquor, Kraft process, Pulp (tooth), Kraft paper, Pulp and paper industry

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