2002•Journal of the American Chemical SocietyRequires access

Formation of a New Crystalline Silicate Structure by Grafting Dialkoxysilyl Groups on Layered Octosilicate

Dai Mochizuki, Atsushi Shimojima, Kazuyuki Kuroda

Abstract

Dialkoxydichlorosilanes ((RO)2SiCl2, R = alkyl) react almost completely with interlayer silanol groups in a layered silicate octosilicate to create a new crystalline silicate structure consisting of new five-membered rings arranged regularly on both sides of the silicate layers. The introduction of dialkoxysilyl groups to the interlamellar region of layered silicates with regular reaction sites provides a new methodology for the design and construction of novel crystalline silicate frameworks by a soft chemical route.

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Key concepts: Silanol, Silicate, Chemistry, Alkyl, Grafting, Chemical engineering, Crystallography, Polymer chemistry