Kinginoside, a New Acyl Group Carrying Iridoid Bioside from Lonicera morrowii.
Norio Aimi, Hideo Seki, Shin‐ichiro Sakai, Joju Haginiwa
Abstract
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Norio Aimi, Hideo Seki, Shin‐ichiro Sakai, Joju Haginiwa
Abstract
Open-access reader
A new iridoid glycoside, kinginoside, was isolated from Lonicera morrowii (Caprifoliaceae). Its structure was deduced to be sweroside-6'-O-(4"-O-feruloyl-α-L-rhamnoside mainly by spectroscopic analysis. The structure was confirmed by chemical synthesis of the corresponding acetate from sweroside of known structure.
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A new iridoid glycoside, kinginoside, was isolated from Lonicera morrowii (Caprifoliaceae). Its structure was deduced to be sweroside-6'-O-(4"-O-feruloyl-α-L-rhamnoside mainly by spectroscopic analysis. The structure was confirmed by chemical synthesis of the corresponding acetate from sweroside of known structure.
Key concepts: Caprifoliaceae, Chemistry, Iridoid, Stereochemistry, Glycoside, Loganin, Aucubin, Group (periodic table)