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Aconic acid and related compounds: II. The reaction of aconic acid with diazomethane

R. F. Rekker, J. P. Brombacher, W. Th. Nauta

Abstract

Abstract From aconic acid with an excess of diazomethane a nitrogen‐containing compound is formed. The structure was established to be methyl 3,4‐(4′,5′‐Δ1‐pyrazolino) aconate. Heating of this compound resulted in the splitting off of a molecule of nitrogen and the formation of a methyl‐substituted aconic acid ester hitherto unknown in the literature.

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Key concepts: Diazomethane, Chemistry, Nitrogen, Molecule, Organic chemistry, Medicinal chemistry