2006•Journal of the American Oil Chemists SocietyRequires access

Glycerolysis of Fatty Acid Methyl Esters: 2. Simulation and Experiments in Continuous Reactors

Devender S. Negi, Tobias Kimmel, Günter Wozny, Reinhard Schomäcker

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Abstract

Abstract The glycerolysis of methyl ester was investigated in flow reactors. This reaction represents a liquid two‐phase reaction with changing reaction rates in a batch reactor. A semi‐empirical model tested earlier with batch reactor data was used to simulate different continuous processes for this reaction. Among the processes simulated, a single continuous‐flow stirred tank reactor (CSTR) without recycling was considered most appropriate for experimental implementation, although simulations showed that a faster reaction rate is possible with the application of a CSTR followed by a tubular reactor with certain associated residence times. The CSTR simulations were verified experimentally. A good agreement was found between the experimental data and simulation results.

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What this paper is about

Abstract The glycerolysis of methyl ester was investigated in flow reactors. This reaction represents a liquid two‐phase reaction with changing reaction rates in a batch reactor. A semi‐empirical model tested earlier with batch reactor data was used to simulate different continuous processes for this reaction. Among the processes simulated, a single continuous‐flow stirred tank reactor (CSTR) without recycling was considered most appropriate for experimental implementation, although simulations showed that a faster reaction rate is possible with the application of a CSTR followed by a tubular reactor with certain associated residence times. The CSTR simulations were verified experimentally. A good agreement was found between the experimental data and simulation results.

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Available abstract

Abstract The glycerolysis of methyl ester was investigated in flow reactors. This reaction represents a liquid two‐phase reaction with changing reaction rates in a batch reactor. A semi‐empirical model tested earlier with batch reactor data was used to simulate different continuous processes for this reaction. Among the processes simulated, a single continuous‐flow stirred tank reactor (CSTR) without recycling was considered most appropriate for experimental implementation, although simulations showed that a faster reaction rate is possible with the application of a CSTR followed by a tubular reactor with certain associated residence times. The CSTR simulations were verified experimentally. A good agreement was found between the experimental data and simulation results.

Key concepts: Continuous stirred-tank reactor, Residence time (fluid dynamics), Plug flow reactor model, Batch reactor, Continuous flow, Continuous reactor, Chemistry, Reactor design

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