Glycerolysis of Fatty Acid Methyl Esters: 2. Simulation and Experiments in Continuous Reactors
Devender S. Negi, Tobias Kimmel, Günter Wozny, Reinhard Schomäcker
Abstract
Devender S. Negi, Tobias Kimmel, Günter Wozny, Reinhard Schomäcker
Abstract
Abstract The glycerolysis of methyl ester was investigated in flow reactors. This reaction represents a liquid two‐phase reaction with changing reaction rates in a batch reactor. A semi‐empirical model tested earlier with batch reactor data was used to simulate different continuous processes for this reaction. Among the processes simulated, a single continuous‐flow stirred tank reactor (CSTR) without recycling was considered most appropriate for experimental implementation, although simulations showed that a faster reaction rate is possible with the application of a CSTR followed by a tubular reactor with certain associated residence times. The CSTR simulations were verified experimentally. A good agreement was found between the experimental data and simulation results.
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Abstract The glycerolysis of methyl ester was investigated in flow reactors. This reaction represents a liquid two‐phase reaction with changing reaction rates in a batch reactor. A semi‐empirical model tested earlier with batch reactor data was used to simulate different continuous processes for this reaction. Among the processes simulated, a single continuous‐flow stirred tank reactor (CSTR) without recycling was considered most appropriate for experimental implementation, although simulations showed that a faster reaction rate is possible with the application of a CSTR followed by a tubular reactor with certain associated residence times. The CSTR simulations were verified experimentally. A good agreement was found between the experimental data and simulation results.
Key concepts: Continuous stirred-tank reactor, Residence time (fluid dynamics), Plug flow reactor model, Batch reactor, Continuous flow, Continuous reactor, Chemistry, Reactor design