1999Chemistry - A European JournalRequires access

The Ozonolysis of Ethylene: A Theoretical Study of the Gas-Phase Reaction Mechanism

Josep M. Anglada, Ramón Crehuet, Josep María Bofill

Open publisher page 140 citations

Abstract

An important source of atmospheric polution, the gas-phase ozonolysis of ethylene, has been submitted to systematic theoretical investigation. Apart from its concerted cleavage to the Criegee intermediates, the ethylene primary ozonide (POZ) decomposes in a stepwise mechanism by the alternative routes shown here.

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What this paper is about

An important source of atmospheric polution, the gas-phase ozonolysis of ethylene, has been submitted to systematic theoretical investigation. Apart from its concerted cleavage to the Criegee intermediates, the ethylene primary ozonide (POZ) decomposes in a stepwise mechanism by the alternative routes shown here.

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Available abstract

An important source of atmospheric polution, the gas-phase ozonolysis of ethylene, has been submitted to systematic theoretical investigation. Apart from its concerted cleavage to the Criegee intermediates, the ethylene primary ozonide (POZ) decomposes in a stepwise mechanism by the alternative routes shown here.

Key concepts: Ozonide, Ozonolysis, Ethylene, Gas phase, Chemistry, Mechanism (biology), Cleavage (geology), Reaction mechanism

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