Steady regimes of exothermic autocatalytic reaction in a continued stirred-tank reactor
Б. Л. Корсунский, N. G. Samoilenko, E. V. Deyun, A. O. Il’chenko
Abstract
Б. Л. Корсунский, N. G. Samoilenko, E. V. Deyun, A. O. Il’chenko
Abstract
A continued stirred-tank reactor with an exothermic autocatalytic reaction running in it is modeled. In contrast to the simple kinetic law formulated in terms of a first-order equation, a variety of possible types of thermal isoclines, including isoles, are found for the autocatalytic process in the dimensionless “degree of conversion-temperature” coordinates. A bifurcation curve separating the domains of existence of one and three steady states is constructed in the Se-Da coordinates.
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A continued stirred-tank reactor with an exothermic autocatalytic reaction running in it is modeled. In contrast to the simple kinetic law formulated in terms of a first-order equation, a variety of possible types of thermal isoclines, including isoles, are found for the autocatalytic process in the dimensionless “degree of conversion-temperature” coordinates. A bifurcation curve separating the domains of existence of one and three steady states is constructed in the Se-Da coordinates.
Key concepts: Exothermic reaction, Autocatalysis, Dimensionless quantity, Continuous stirred-tank reactor, Thermodynamics, Autocatalytic reaction, Bifurcation, Kinetic energy