1990Journal of the Chemical Society Chemical CommunicationsRequires access

Ion-molecule pairs in solvolysis. Trapping of an anthranyl carbocation molecule pair by solvent water

Alf Thibblin

Open publisher page 10 citations

Abstract

The specific acid-catalysed solvolysis of 9-benzylidene-10-methoxy-10-methyl-9,10-dihydroanthracene (1-OMe) in mixtures of water and acetonitrile proceeds mainly via a localized carbocation-molecule pair intermediate.

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The specific acid-catalysed solvolysis of 9-benzylidene-10-methoxy-10-methyl-9,10-dihydroanthracene (1-OMe) in mixtures of water and acetonitrile proceeds mainly via a localized carbocation-molecule pair intermediate.

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Available abstract

The specific acid-catalysed solvolysis of 9-benzylidene-10-methoxy-10-methyl-9,10-dihydroanthracene (1-OMe) in mixtures of water and acetonitrile proceeds mainly via a localized carbocation-molecule pair intermediate.

Key concepts: Carbocation, Solvolysis, Chemistry, Molecule, Solvent, Acetonitrile, Ion, Photochemistry

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