Ion-molecule pairs in solvolysis. Trapping of an anthranyl carbocation molecule pair by solvent water
Alf Thibblin
Abstract
Alf Thibblin
Abstract
The specific acid-catalysed solvolysis of 9-benzylidene-10-methoxy-10-methyl-9,10-dihydroanthracene (1-OMe) in mixtures of water and acetonitrile proceeds mainly via a localized carbocation-molecule pair intermediate.
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The specific acid-catalysed solvolysis of 9-benzylidene-10-methoxy-10-methyl-9,10-dihydroanthracene (1-OMe) in mixtures of water and acetonitrile proceeds mainly via a localized carbocation-molecule pair intermediate.
Key concepts: Carbocation, Solvolysis, Chemistry, Molecule, Solvent, Acetonitrile, Ion, Photochemistry