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2015•Chemistry - A European JournalOpen access

Back Cover: Enhanced Electrochemiluminescence from a Stoichiometric Ruthenium(II)–Iridium(III) Complex Soft Salt (Chem. Eur. J. 20/2015)

Kalen N. Swanick, Martina Sandroni, Zhifeng Ding, Eli Zysman‐Colman

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Abstract

The electrochemiluminescence (ECL) of the soft salt [Ru(dtbubpy)3][Ir(ppy)2(CN)2]2 ([Ir][Ru][Ir]), composed of an anionic iridium complex and a cationic ruthenium complex, is presented. Light emission takes place exclusively from the ruthenium complex excited state, and is generated by annihilation between oxidized [Ir] and reduced [Ru]. This heterometallic system is anticipated to be attractive for the development of efficient and low-energy-cost ECL detection systems. For more details see the Full Paper by E. Zysman-Colman, Z. Ding et al. on page 7435 ff.

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The electrochemiluminescence (ECL) of the soft salt [Ru(dtbubpy)3][Ir(ppy)2(CN)2]2 ([Ir][Ru][Ir]), composed of an anionic iridium complex and a cationic ruthenium complex, is presented. Light emission takes place exclusively from the ruthenium complex excited state, and is generated by annihilation between oxidized [Ir] and reduced [Ru]. This heterometallic system is anticipated to be attractive for the development of efficient and low-energy-cost ECL detection systems. For more details see the Full Paper by E. Zysman-Colman, Z. Ding et al. on page 7435 ff.

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Available abstract

The electrochemiluminescence (ECL) of the soft salt [Ru(dtbubpy)3][Ir(ppy)2(CN)2]2 ([Ir][Ru][Ir]), composed of an anionic iridium complex and a cationic ruthenium complex, is presented. Light emission takes place exclusively from the ruthenium complex excited state, and is generated by annihilation between oxidized [Ir] and reduced [Ru]. This heterometallic system is anticipated to be attractive for the development of efficient and low-energy-cost ECL detection systems. For more details see the Full Paper by E. Zysman-Colman, Z. Ding et al. on page 7435 ff.

Key concepts: Ruthenium, Iridium, Electrochemiluminescence, Cationic polymerization, Salt (chemistry), Excited state, Chemistry, Stoichiometry

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Back Cover: Enhanced Electrochemiluminescence from a Stoichiometric Ruthenium(II)–Iridium(III) Complex Soft Salt (Chem. Eur. J. 20/2015) — Research Paper | ScholarLens