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1962•The Journal of Chemical PhysicsRequires access

Photolysis of Nitrous Oxide. II. 1470 and 1830 A

J. P. Doering, Bruce H. Mahan

Open publisher page 29 citations

Abstract

The photolysis of N15NO and NN15O have been investigated using 1470- and 1830-A light. The products include small amounts of N230, as well as N229. The appearance of N230 shows that there are two primary processes occurring, one of which is the dissociation to a nitrogen atom and a nitric oxide molecule, the other dissociation to an oxygen atom and a nitrogen molecule. In addition, at 1470 A a photoexcited molecule is formed which is capable of dissociating another nitrous oxide molecule.

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What this paper is about

The photolysis of N15NO and NN15O have been investigated using 1470- and 1830-A light. The products include small amounts of N230, as well as N229. The appearance of N230 shows that there are two primary processes occurring, one of which is the dissociation to a nitrogen atom and a nitric oxide molecule, the other dissociation to an oxygen atom and a nitrogen molecule. In addition, at 1470 A a photoexcited molecule is formed which is capable of dissociating another nitrous oxide molecule.

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Available abstract

The photolysis of N15NO and NN15O have been investigated using 1470- and 1830-A light. The products include small amounts of N230, as well as N229. The appearance of N230 shows that there are two primary processes occurring, one of which is the dissociation to a nitrogen atom and a nitric oxide molecule, the other dissociation to an oxygen atom and a nitrogen molecule. In addition, at 1470 A a photoexcited molecule is formed which is capable of dissociating another nitrous oxide molecule.

Key concepts: Photodissociation, Dissociation (chemistry), Nitrous oxide, Molecule, Photochemistry, Chemistry, Nitrogen, Nitrogen atom

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