1987Berichte der Bunsengesellschaft für physikalische ChemieRequires access

Single Crystals from Optically Active Diacetylenes and Polydiacetylenes

C. Kröhnke

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Abstract

Abstract Diacetylene monomers with chiral side groups have been synthetized. The monomer crystals polymerize upon irradiation or thermal annealing. The thermal polymerization was studied and the potential use of the resulting polymer crystals as optical devices was discussed. A characterization of the monomers and one polymer in solution with regard to specific rotation was obtained.

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Abstract Diacetylene monomers with chiral side groups have been synthetized. The monomer crystals polymerize upon irradiation or thermal annealing. The thermal polymerization was studied and the potential use of the resulting polymer crystals as optical devices was discussed. A characterization of the monomers and one polymer in solution with regard to specific rotation was obtained.

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Available abstract

Abstract Diacetylene monomers with chiral side groups have been synthetized. The monomer crystals polymerize upon irradiation or thermal annealing. The thermal polymerization was studied and the potential use of the resulting polymer crystals as optical devices was discussed. A characterization of the monomers and one polymer in solution with regard to specific rotation was obtained.

Key concepts: Diacetylene, Polydiacetylenes, Monomer, Polymerization, Polymer, Materials science, Irradiation, Thermal

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