Paul Müller, Jean‐Claude Perlberger
Abstract
Abstract The activation parameters for the oxidation of 13 secondary alcohols with chromic acid have been determined. Application of a statistical treatment of Exner [9] shows that the reactions are isoentropic with an average entropy of activation (ΔS≠) of −24.0 e. u.
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Abstract The activation parameters for the oxidation of 13 secondary alcohols with chromic acid have been determined. Application of a statistical treatment of Exner [9] shows that the reactions are isoentropic with an average entropy of activation (ΔS≠) of −24.0 e. u.
Key concepts: Chromic acid, Chemistry, Alcohol, Alcohol oxidation, Entropy (arrow of time), Organic chemistry, Thermodynamics, Physics