Yuji Mori, Hiroshi Furukawa
Abstract
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Cryptocaryalactone, a 1, 3-polyol-derived α, β-unsaturated δ-lactone, has been synthesized in a stereocontrolled manner via the coupling reaction of a chiral dithiane with an epoxide and anti-stereoselective 1, 3-asymmetric reduction of the derived hydroxy ketone.
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Cryptocaryalactone, a 1, 3-polyol-derived α, β-unsaturated δ-lactone, has been synthesized in a stereocontrolled manner via the coupling reaction of a chiral dithiane with an epoxide and anti-stereoselective 1, 3-asymmetric reduction of the derived hydroxy ketone.
Key concepts: Chemistry, Polyol, Epoxide, Lactone, Stereoselectivity, Ketone, Dithiane, Stereochemistry