MOLECULAR INTERACTIONS BETWEEN SUBSTITUTED 3-AMINOMETHYLBENZIMIDAZOLE-2-THIOLS AND TETRACYANOETHYLENE
Alaa A. Hassan
Abstract
Alaa A. Hassan
Abstract
The charge-transfer (CT) complexes of substituted 3-aminomethylbenzimidazole-2-thiols 1a–h as donors with tetracyanoethylene (TCNE) as π-acceptors were studied spectrophotometrically. The stability constants of the complexes were affected by substituents and solvent polarities as well as the thermodynamic properties likewise ΔG, ΔH and ΔS.
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The charge-transfer (CT) complexes of substituted 3-aminomethylbenzimidazole-2-thiols 1a–h as donors with tetracyanoethylene (TCNE) as π-acceptors were studied spectrophotometrically. The stability constants of the complexes were affected by substituents and solvent polarities as well as the thermodynamic properties likewise ΔG, ΔH and ΔS.
Key concepts: Tetracyanoethylene, Chemistry, Charge (physics), Solvent, Computational chemistry, Polymer chemistry, Medicinal chemistry, Organic chemistry