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2010•The Journal of Organic ChemistryRequires access

Preparation of NHC Borane Complexes by Lewis Base Exchange with Amine− and Phosphine−Boranes

Malika Makhlouf Brahmi, Julien Monot, Marine Desage‐El Murr, Dennis P. Curran, Louis Fensterbank, Emmanuel Lacôte, Max Malacrìa

Open publisher page 66 citations

Abstract

A versatile new method for the preparation of NHC boranes starting from two stable, readily available reactants-an heterocyclic salt and an amine or phosphine-borane-is reported. It uses a Lewis base exchange at boron and provides easy access to new NHC boranes, in particular B-substituted borane ones.

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What this paper is about

A versatile new method for the preparation of NHC boranes starting from two stable, readily available reactants-an heterocyclic salt and an amine or phosphine-borane-is reported. It uses a Lewis base exchange at boron and provides easy access to new NHC boranes, in particular B-substituted borane ones.

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OpenAlex reports 66 citations for this work. Citation counts describe recorded attention and do not establish research quality.

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Available abstract

A versatile new method for the preparation of NHC boranes starting from two stable, readily available reactants-an heterocyclic salt and an amine or phosphine-borane-is reported. It uses a Lewis base exchange at boron and provides easy access to new NHC boranes, in particular B-substituted borane ones.

Key concepts: Boranes, Chemistry, Borane, Phosphine, Lewis acids and bases, Amine gas treating, Organic chemistry, Base (topology)

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