1999•Molecular PhysicsRequires access

Relativistic chemical shielding: formally exact solutions for one—electron atoms of maximum total angular momentum for any principal quantum number

Elaine A. Moore

Abstract

Analytical solutions have been derived for the chemical shieding of one-electron atoms in states of maximum total angular momentum (j = n -1/2). The variation of terms connecting states of different angular momentum is discussed as a function of the quantum numbers, k(= n), j and m the magnetic quantum number, and of Z, the atomic number.

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Key concepts: Total angular momentum quantum number, Hydrogen-like atom, Principal quantum number, Angular momentum, Angular momentum coupling, Quantum number, Electron, Azimuthal quantum number