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1978•Journal of the Chemical Society Chemical CommunicationsRequires access

Intramolecular photochemical cycloadditions involving enolised cyclopentane-1,3-diones. A new approach to the bicyclo[3.2.1]octane ring system

Michael Mellor, Dismas A. Otieno, Gerald Pattenden

Open publisher page 16 citations

Abstract

Irradiation of the enol acetates derived from several substituted 4-(prop-2-enyl)cyclopentane-1,3-diones leads to photoproducts resulting from intramolecular [2 + 2] cycloaddition, which can then be elaborated to the bicyclo[3.2.1]octane ring system.

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What this paper is about

Irradiation of the enol acetates derived from several substituted 4-(prop-2-enyl)cyclopentane-1,3-diones leads to photoproducts resulting from intramolecular [2 + 2] cycloaddition, which can then be elaborated to the bicyclo[3.2.1]octane ring system.

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OpenAlex reports 16 citations for this work. Citation counts describe recorded attention and do not establish research quality.

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Available abstract

Irradiation of the enol acetates derived from several substituted 4-(prop-2-enyl)cyclopentane-1,3-diones leads to photoproducts resulting from intramolecular [2 + 2] cycloaddition, which can then be elaborated to the bicyclo[3.2.1]octane ring system.

Key concepts: Cyclopentane, Octane, Bicyclic molecule, Cycloaddition, Intramolecular force, Chemistry, Ring (chemistry), Enol

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Intramolecular photochemical cycloadditions involving enolised cyclopentane-1,3-diones. A new approach to the bicyclo[3.2.1]octane ring system — Research Paper | ScholarLens