2005•European Journal of Organic ChemistryRequires access

Dimethyldioxirane and Acetone Are Not in Equilibrium

Klaus‐Peter Zeller, Meike Kowallik, Paul Schüler

Abstract

Abstract The potential transfer of an oxygen atom from dioxiranes to a ketonic carbonyl group is disproved by appropriate D‐ and 13C‐labelling. As shown by 13C NMR spectroscopy bis(trideuteriomethyl)dioxirane and [carbonyl‐13C]acetone are not in equilibrium with [D6]acetone and [3‐13C]dimethyldioxirane. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

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Key concepts: Dimethyldioxirane, Dioxirane, Chemistry, Acetone, Carbonyl group, Ketone, Oxygen atom, Nuclear magnetic resonance spectroscopy