1973Journal of the Chemical Society Chemical CommunicationsRequires access

The association of the Claisen rearrangement with a novel [1,5] sigmatropic rearrangement

Christopher P. Falshaw, Susan A. Lane, W. David Ollis

Open publisher page 4 citations

Abstract

Thermal rearrangement of the allyl aryl ether (5) gave, in addition to the expected Claisen rearrangement product (6), the isomer (7), and similarly thermal transformation of the allyl ether (8) gave the mixture (9) and (10); the formation of (7) and (10) is rationalised as involving a [1,5] acetyl shift.

About this research paper

What this paper is about

Thermal rearrangement of the allyl aryl ether (5) gave, in addition to the expected Claisen rearrangement product (6), the isomer (7), and similarly thermal transformation of the allyl ether (8) gave the mixture (9) and (10); the formation of (7) and (10) is rationalised as involving a [1,5] acetyl shift.

Why it matters

OpenAlex reports 4 citations for this work. Citation counts describe recorded attention and do not establish research quality.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

Thermal rearrangement of the allyl aryl ether (5) gave, in addition to the expected Claisen rearrangement product (6), the isomer (7), and similarly thermal transformation of the allyl ether (8) gave the mixture (9) and (10); the formation of (7) and (10) is rationalised as involving a [1,5] acetyl shift.

Key concepts: Sigmatropic reaction, Claisen rearrangement, Carroll rearrangement, Ether, Chemistry, Cope rearrangement, Aryl, Stereochemistry

Related papers

Back to paper searchBrowse research topicsOriginal source
The association of the Claisen rearrangement with a novel [1,5] sigmatropic rearrangement — Research Paper | ScholarLens