1985•Journal of the Chemical Society Chemical CommunicationsRequires access

Formation of condensed tetraydrofurans in the oxidation of norbornene by bis(acetonitrile)chloronitropalladium(II)

Pui Kwan Wong, Mark K. Dickson, Larry L. Sterna

Abstract

The (MeCN)2PdCl(NO2)-catalysed air oxidation of norbornene gives nearly exclusively exo-epoxynorbornene at low norbornene concentrations but predominantly condensed tetrahydrofurans derived from two norbornene units and one oxygen atom at high norbornene concentrations.

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Key concepts: Norbornene, Acetonitrile, Chemistry, Oxygen atom, Oxygen, Polymer chemistry, Photochemistry, Organic chemistry