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1978•Journal of the Chemical Society Chemical CommunicationsRequires access

Solvolysis of substituted benzylidene chlorides in dioxan–water; an unusual role for a distant carboxy-group in a carbonium ion reaction

V. P. Vitullo, R. J. Capp

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Abstract

Evidence is presented which points to the existence of a spiro-intermediate in the solvolysis of p-KO2CCH2OC6H4CHCl2 in dioxan–water mixtures.

About this research paper

What this paper is about

Evidence is presented which points to the existence of a spiro-intermediate in the solvolysis of p-KO2CCH2OC6H4CHCl2 in dioxan–water mixtures.

Why it matters

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Key contribution

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Method / approach

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Main findings

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Available abstract

Evidence is presented which points to the existence of a spiro-intermediate in the solvolysis of p-KO2CCH2OC6H4CHCl2 in dioxan–water mixtures.

Key concepts: Solvolysis, Carbonium ion, Chemistry, Group (periodic table), Ion, Medicinal chemistry, Organic chemistry, Hydrolysis

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Solvolysis of substituted benzylidene chlorides in dioxan–water; an unusual role for a distant carboxy-group in a carbonium ion reaction — Research Paper | ScholarLens