1990Rapid Communications in Mass SpectrometryRequires access

Collision‐energy ramp. A modification to an RF‐only quadrupole collision cell

Geoffrey Bott, Sherri Ogden, Julie A. Leary

Open publisher page 7 citations

Abstract

Abstract A modification to the electronics controlling the collision energy of an RF‐only quadrupole collision cell in a BEqQ geometry mass spectrometer is described. The modification allows the collision energy to be ramped from 0–500 eV while scanning the quadrupole mass analyser. The collision‐induced dissociation spectra generated using a ramped collision energy exhibit a 10%–100% increase in product‐ion abundance.

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What this paper is about

Abstract A modification to the electronics controlling the collision energy of an RF‐only quadrupole collision cell in a BEqQ geometry mass spectrometer is described. The modification allows the collision energy to be ramped from 0–500 eV while scanning the quadrupole mass analyser. The collision‐induced dissociation spectra generated using a ramped collision energy exhibit a 10%–100% increase in product‐ion abundance.

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Available abstract

Abstract A modification to the electronics controlling the collision energy of an RF‐only quadrupole collision cell in a BEqQ geometry mass spectrometer is described. The modification allows the collision energy to be ramped from 0–500 eV while scanning the quadrupole mass analyser. The collision‐induced dissociation spectra generated using a ramped collision energy exhibit a 10%–100% increase in product‐ion abundance.

Key concepts: Collision, Chemistry, Analyser, Collision-induced dissociation, Quadrupole, Mass spectrometry, Atomic physics, Triple quadrupole mass spectrometer

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