Solution of Schrödinger equation by Laplace transform
M. J. Englefield
Abstract
Open-access reader
M. J. Englefield
Abstract
Open-access reader
Laplace transform techniques for solving differential equations do not seem to have been directly applied to the Schrödinger equation in quantum mechanics. This may be because the Laplace transform of a wave function, in contrast to the Fourier transform, has no direct physical significance. However, this paper will show that scattering phase shifts and bound state energies can be determined from the singularities of the Laplace transform of the wave function. The Laplace transform method can thereby simplify calculations if the potential allows a straightforward solution of the transformed Schrödinger equation. Suitable cases are the Coulomb, oscillator and exponential potentials and the Yamaguchi separable non-local potential.
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Laplace transform techniques for solving differential equations do not seem to have been directly applied to the Schrödinger equation in quantum mechanics. This may be because the Laplace transform of a wave function, in contrast to the Fourier transform, has no direct physical significance. However, this paper will show that scattering phase shifts and bound state energies can be determined from the singularities of the Laplace transform of the wave function. The Laplace transform method can thereby simplify calculations if the potential allows a straightforward solution of the transformed Schrödinger equation. Suitable cases are the Coulomb, oscillator and exponential potentials and the Yamaguchi separable non-local potential.
Key concepts: Laplace transform applied to differential equations, Two-sided Laplace transform, Laplace transform, Inverse Laplace transform, Mellin transform, Green's function for the three-variable Laplace equation, Mathematical analysis, Fourier transform