1967•Journal of the Chemical Society C OrganicRequires access

Optical rotatory dispersion. Part XLVIII. Some 3,3-diarylprop-1-enes and related quinones: the absolute configuration of latifolin

Dervilla M. X. Donnelly, B.J. Nangle, Peter B. Hulbert, William Klyne, R. J. Swan

Abstract

The optical rotatory dispersion (o.r.d.) curves of latifolin and its derivatives, which are substituted 3,3-diarylprop-1-enes, have been compared in the short wavelength region with those of related quinol diacetates of known absolute configuration; the characteristic Cotton effects at 235 mµ show that the absolute configuration of latifolin is R. The o.r.d. curves of the related quinones of the dalbergione series confirm this assignment.

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Key concepts: Absolute configuration, Optical rotatory dispersion, Absolute (philosophy), Chemistry, Dispersion (optics), Wavelength, Stereochemistry, Physics