Infrared Spectra and Photochemistry of Isodiazene and Its Deuterated Isotopomers
J. Henrique Teles, Günther Maier, B. Andes Hess, L. J. Schaad
Abstract
J. Henrique Teles, Günther Maier, B. Andes Hess, L. J. Schaad
Abstract
Abstract The matrix isolation of aminoisocyanate opens a new efficient route for the preparation of isodiazene (aminonitrene). Its infrared spectrum can now, with the help of ab initio calculations, be interpreted, and its photochemistry can be studied.
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Abstract The matrix isolation of aminoisocyanate opens a new efficient route for the preparation of isodiazene (aminonitrene). Its infrared spectrum can now, with the help of ab initio calculations, be interpreted, and its photochemistry can be studied.
Key concepts: Isotopomers, Chemistry, Matrix isolation, Infrared, Deuterium, Infrared spectroscopy, Ab initio quantum chemistry methods, Photochemistry