2000•Journal of the Chemical Society Dalton TransactionsRequires access

Four-co-ordinated copper(II) species obtained by X-ray irradiation of a three-co-ordinated copper(I) complex: a single crystal EPR study

Cornelia G. Palivan, Sundara Ramaprabhu

Abstract

X-Ray irradiation of a single crystal of chlorobis(1-isopropylimidazolidine-2-thione)copper(I) led to the formation of two copper(II) species whose structures were studied by EPR spectroscopy. The EPR parameters provide information on the structural changes which characterize the formation of the four-co-ordinated copper(II) species when the three-co-ordinated copper(I) precursor reacts with radiogenic radicals formed during the irradiation and provide insight into the reaction mechanism.

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Key concepts: Electron paramagnetic resonance, Copper, Irradiation, Radical, Chemistry, Single crystal, Crystallography, Crystal (programming language)