1995•Acta Crystallographica Section C Crystal Structure CommunicationsRequires access

Tris(n-butyl)phosphine, Tris(tert-butyl)phosphine and Tris(trimethylsilyl)phosphine

J. Bruckmann, Carsten Krüger

Abstract

Single crystals of the title compounds, C 12 H 27 P (1), C 12 H 27 P (2), and C 9 H 27 PSi 3 (3), were grown in capillaries at low temperature using zone-melting techniques [Brodalla, Mootz, Boese & Osswald (1985). J. Appl. Cryst. 18, 316-319]. The molecular and crystal structures of all three compounds were determined at 102 K. Compound (1) has a pseudo-mirror plane and C-P-C angles between 100.5(1) and 102.7(1)°. Compound (2) has a pseudosymmetric threefold rotation axis and C-P-C angles of 107.1(1), 107.4(1) and 107.8 (1)°. Isomorphous compound (3) has Si-P-Si angles between 105.8 (1) and 106.5 (1)°.

About this research paper

What this paper is about

Why it matters

OpenAlex reports 22 citations for this work. Citation counts describe recorded attention and do not establish research quality.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

Key concepts: Phosphine, Tris, Trimethylsilyl, Chemistry, Crystallography, Crystal structure, Medicinal chemistry, Organic chemistry