Hydroxylation of benzene in the system vanadium(V)-hydrogen peroxide-acetic acid
N. I. Rudakova, M. V. Klyuev, Yu. G. Erykalov, D. N. Ramazanov
Abstract
N. I. Rudakova, M. V. Klyuev, Yu. G. Erykalov, D. N. Ramazanov
Abstract
Hydroxylation of benzene in acetic acid at 323 K was studied in the presence of a sodium orthovanadate catalyst. With hydrogen peroxide as aqueous solution, the yield of phenol was 12–14%. With hydrogen peroxide generated from dry sodium peroxide, the yield of phenol could be improved to 21–23%. The apparent decomposition rate constants of hydrogen peroxide in acetic acid are presented.
OpenAlex reports 13 citations for this work. Citation counts describe recorded attention and do not establish research quality.
A contribution statement is not available in the OpenAlex record.
Method details are not available in the OpenAlex metadata.
Findings are not separately available in the OpenAlex metadata.
Limitations are not available in the OpenAlex metadata.
Application details are not available in the OpenAlex metadata.
Hydroxylation of benzene in acetic acid at 323 K was studied in the presence of a sodium orthovanadate catalyst. With hydrogen peroxide as aqueous solution, the yield of phenol was 12–14%. With hydrogen peroxide generated from dry sodium peroxide, the yield of phenol could be improved to 21–23%. The apparent decomposition rate constants of hydrogen peroxide in acetic acid are presented.
Key concepts: Chemistry, Hydrogen peroxide, Benzene, Hydroxylation, Acetic acid, Phenol, Catalysis, Yield (engineering)