Specific heat of a one-dimensional carbon phase synthesized by condensation of high-temperature carbon gas
Andrei V. Palnichenko, A. F. Gurov, V. N. Kopylov, K. Kusano, Sei‐ichi Tanuma, E. I. Salamatov
Abstract
Andrei V. Palnichenko, A. F. Gurov, V. N. Kopylov, K. Kusano, Sei‐ichi Tanuma, E. I. Salamatov
Abstract
We report on the specific heat, $C(T)$, measurements in the temperature ranges 4.5 K $<T<$ 30 K and 130 K $<T<$ 730 K of a one-dimensional carbon crystal phase synthesized by condensation of high-temperature carbon gas. Even at the lowest achieved temperatures, the measured $C(T)$ dependence, to the first approximation, is close to the linear dependence over the wide temperature range from 15 K to 30 K. For the adequate description of the measured low-temperature $C(T)$ dependence, the chainlike crystal structure of the material has been considered, and the model of specific heat for quasi-one-dimensional crystals has been applied. By means of x-ray and high-temperature specific-heat measurements it has been found that the material is a metastable phase under the normal conditions, undergoing complicated irreversible transformations to the amorphous state upon heating above $T\ensuremath{\approx}350$ K.
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We report on the specific heat, $C(T)$, measurements in the temperature ranges 4.5 K $<T<$ 30 K and 130 K $<T<$ 730 K of a one-dimensional carbon crystal phase synthesized by condensation of high-temperature carbon gas. Even at the lowest achieved temperatures, the measured $C(T)$ dependence, to the first approximation, is close to the linear dependence over the wide temperature range from 15 K to 30 K. For the adequate description of the measured low-temperature $C(T)$ dependence, the chainlike crystal structure of the material has been considered, and the model of specific heat for quasi-one-dimensional crystals has been applied. By means of x-ray and high-temperature specific-heat measurements it has been found that the material is a metastable phase under the normal conditions, undergoing complicated irreversible transformations to the amorphous state upon heating above $T\ensuremath{\approx}350$ K.
Key concepts: Metastability, Condensation, Materials science, Atmospheric temperature range, Carbon fibers, Thermodynamics, Phase (matter), Crystal (programming language)