1997Physical review. B, Condensed matterRequires access

Specific heat of a one-dimensional carbon phase synthesized by condensation of high-temperature carbon gas

Andrei V. Palnichenko, A. F. Gurov, V. N. Kopylov, K. Kusano, Sei‐ichi Tanuma, E. I. Salamatov

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Abstract

We report on the specific heat, $C(T)$, measurements in the temperature ranges 4.5 K $<T<$ 30 K and 130 K $<T<$ 730 K of a one-dimensional carbon crystal phase synthesized by condensation of high-temperature carbon gas. Even at the lowest achieved temperatures, the measured $C(T)$ dependence, to the first approximation, is close to the linear dependence over the wide temperature range from 15 K to 30 K. For the adequate description of the measured low-temperature $C(T)$ dependence, the chainlike crystal structure of the material has been considered, and the model of specific heat for quasi-one-dimensional crystals has been applied. By means of x-ray and high-temperature specific-heat measurements it has been found that the material is a metastable phase under the normal conditions, undergoing complicated irreversible transformations to the amorphous state upon heating above $T\ensuremath{\approx}350$ K.

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What this paper is about

We report on the specific heat, $C(T)$, measurements in the temperature ranges 4.5 K $<T<$ 30 K and 130 K $<T<$ 730 K of a one-dimensional carbon crystal phase synthesized by condensation of high-temperature carbon gas. Even at the lowest achieved temperatures, the measured $C(T)$ dependence, to the first approximation, is close to the linear dependence over the wide temperature range from 15 K to 30 K. For the adequate description of the measured low-temperature $C(T)$ dependence, the chainlike crystal structure of the material has been considered, and the model of specific heat for quasi-one-dimensional crystals has been applied. By means of x-ray and high-temperature specific-heat measurements it has been found that the material is a metastable phase under the normal conditions, undergoing complicated irreversible transformations to the amorphous state upon heating above $T\ensuremath{\approx}350$ K.

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Available abstract

We report on the specific heat, $C(T)$, measurements in the temperature ranges 4.5 K $<T<$ 30 K and 130 K $<T<$ 730 K of a one-dimensional carbon crystal phase synthesized by condensation of high-temperature carbon gas. Even at the lowest achieved temperatures, the measured $C(T)$ dependence, to the first approximation, is close to the linear dependence over the wide temperature range from 15 K to 30 K. For the adequate description of the measured low-temperature $C(T)$ dependence, the chainlike crystal structure of the material has been considered, and the model of specific heat for quasi-one-dimensional crystals has been applied. By means of x-ray and high-temperature specific-heat measurements it has been found that the material is a metastable phase under the normal conditions, undergoing complicated irreversible transformations to the amorphous state upon heating above $T\ensuremath{\approx}350$ K.

Key concepts: Metastability, Condensation, Materials science, Atmospheric temperature range, Carbon fibers, Thermodynamics, Phase (matter), Crystal (programming language)

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