1973Organic Magnetic ResonanceRequires access

Free radicals in the reactions of organic cations

N. N. Bubnov, B. Ya. Medvedev, L. A. Polyakova, K. A. Bilevich, O. Yu. Okhlobystin

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Abstract

Abstract By using the ESR and CIDNP methods the formation of free radicals in the reaction of nucleophilic and electrophilic substitution is proved. The role of free radicals in the mechanism of these reactions is discussed.

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What this paper is about

Abstract By using the ESR and CIDNP methods the formation of free radicals in the reaction of nucleophilic and electrophilic substitution is proved. The role of free radicals in the mechanism of these reactions is discussed.

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OpenAlex reports 7 citations for this work. Citation counts describe recorded attention and do not establish research quality.

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Available abstract

Abstract By using the ESR and CIDNP methods the formation of free radicals in the reaction of nucleophilic and electrophilic substitution is proved. The role of free radicals in the mechanism of these reactions is discussed.

Key concepts: Radical, CIDNP, Chemistry, Photochemistry, Electrophile, Radical substitution, Radical disproportionation, Nucleophile

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