1979The Journal of Chemical PhysicsRequires access

Zeeman–quadrupole cross relaxation between two nuclear spin species

Harold T. Stokesa, David C. Ailion

Open publisher page 23 citations

Abstract

We derive an expression for the rate τ−1IS of the cross relaxation between the Zeeman splitting of one nuclear spin species (I spins, I=1/2) and the quadrupole splitting of another spin species (S spins, S≳1/2) via the I–S dipolar interaction. We calculate τIS for the case of CFCL2–CFCL2 (I spins are 19F, and S spins are 35Cl and 37Cl) and compare the results with experimental data.

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What this paper is about

We derive an expression for the rate τ−1IS of the cross relaxation between the Zeeman splitting of one nuclear spin species (I spins, I=1/2) and the quadrupole splitting of another spin species (S spins, S≳1/2) via the I–S dipolar interaction. We calculate τIS for the case of CFCL2–CFCL2 (I spins are 19F, and S spins are 35Cl and 37Cl) and compare the results with experimental data.

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Available abstract

We derive an expression for the rate τ−1IS of the cross relaxation between the Zeeman splitting of one nuclear spin species (I spins, I=1/2) and the quadrupole splitting of another spin species (S spins, S≳1/2) via the I–S dipolar interaction. We calculate τIS for the case of CFCL2–CFCL2 (I spins are 19F, and S spins are 35Cl and 37Cl) and compare the results with experimental data.

Key concepts: Spins, Zeeman effect, Quadrupole, Nuclear quadrupole resonance, Relaxation (psychology), Spin (aerodynamics), Dipole, Physics

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