Polymerization of isocyanates. V. Thermal degradation of polyisocyanates
Yoshio Iwakura, Keikichi Uno, Norio Kobayashi
Abstract
Yoshio Iwakura, Keikichi Uno, Norio Kobayashi
Abstract
Abstract Thermal degradation of polyisocyanates was investigated. The only degradation products were monomer and trimer. The main product was trimer for most aliphatic polymers, and monomer for aromatic polymers. Poly(cyclohexyl isocyanate) gave only its monomer on account of steric requirements. The apparent activation energy was calculated for aromatic polymers by using TGA and DTA curves.
OpenAlex reports 13 citations for this work. Citation counts describe recorded attention and do not establish research quality.
A contribution statement is not available in the OpenAlex record.
Method details are not available in the OpenAlex metadata.
Findings are not separately available in the OpenAlex metadata.
Limitations are not available in the OpenAlex metadata.
Application details are not available in the OpenAlex metadata.
Abstract Thermal degradation of polyisocyanates was investigated. The only degradation products were monomer and trimer. The main product was trimer for most aliphatic polymers, and monomer for aromatic polymers. Poly(cyclohexyl isocyanate) gave only its monomer on account of steric requirements. The apparent activation energy was calculated for aromatic polymers by using TGA and DTA curves.
Key concepts: Trimer, Monomer, Isocyanate, Polymer chemistry, Polymer, Polymerization, Steric effects, Degradation (telecommunications)