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ChemInform Abstract: USE OF η6‐ARYLPHOSPHINE COMPLEXES OF MOLYBDENUM(0) FOR THE SYNTHESIS OF COMPLEXES CONTAINING MOLYBDENUM‐MOLYBDENUM AND MOLYBDENUM‐TUNGSTEN QUADRUPLE BONDS

Rudy L. Luck, Robert H. Morris

Abstract

Abstract Die Reaktion des Mo(O)‐Komplexes (I), in dem ein Phosphin über einen der Pheny1‐Substituenten koordiniert ist, mit MoCl4(TH F); oder WCl4(PPh3)2 ergibt den homo‐ bzw. heterozweikernigen Komplex (II) und (IV) mit einer Vierfachbindung zwischen beiden Metallen ohne unterstützende Brückenliganden.

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Key concepts: Molybdenum, Tungsten, Chemistry, Polymer chemistry, Inorganic chemistry, Organic chemistry