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Experimental Determinations of the Excluded-Volume Exponent in Different Environments

J. P. Cotton, D. Decker, Bernard Farnoux, G. Jannink, R. Ober, C. Picot

Open publisher page 60 citations

Abstract

The excluded-volume exponent $\ensuremath{\nu}$ is determined from a neutron scattering experiment by polystyrene chains, in the "intermediate" momentum-transfer range. The chains were successively dispersed in a good solvent, in a $\ensuremath{\Theta}$ solvent, and in the bulk material. The new result is the value of $\ensuremath{\nu}$ for the bulk material, which is discussed below.

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The excluded-volume exponent $\ensuremath{\nu}$ is determined from a neutron scattering experiment by polystyrene chains, in the "intermediate" momentum-transfer range. The chains were successively dispersed in a good solvent, in a $\ensuremath{\Theta}$ solvent, and in the bulk material. The new result is the value of $\ensuremath{\nu}$ for the bulk material, which is discussed below.

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Available abstract

The excluded-volume exponent $\ensuremath{\nu}$ is determined from a neutron scattering experiment by polystyrene chains, in the "intermediate" momentum-transfer range. The chains were successively dispersed in a good solvent, in a $\ensuremath{\Theta}$ solvent, and in the bulk material. The new result is the value of $\ensuremath{\nu}$ for the bulk material, which is discussed below.

Key concepts: Exponent, Volume (thermodynamics), Excluded volume, Solvent, Polystyrene, Range (aeronautics), Materials science, Momentum (technical analysis)

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