Molecular recognition of the imidazole residue by a dicopper(II) complex with a bisdien macrocycle bearing two pendant arms
Luigi Fabbrizzi, Piersandro Pallavicini, Luisa Vetter Parodi, Angelo Perotti, Angelo Taglietti
Abstract
Luigi Fabbrizzi, Piersandro Pallavicini, Luisa Vetter Parodi, Angelo Perotti, Angelo Taglietti
Abstract
The dicopper(II) macrocyclic complex 4 tightly binds the imidazolate ion in aqueous solution at pH 9 and recognises molecules containing an imidazole fragment, e.g.L-histidine, in the presence of any other amino acid.
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The dicopper(II) macrocyclic complex 4 tightly binds the imidazolate ion in aqueous solution at pH 9 and recognises molecules containing an imidazole fragment, e.g.L-histidine, in the presence of any other amino acid.
Key concepts: Imidazole, Imidazolate, Histidine, Residue (chemistry), Chemistry, Stereochemistry, Molecule, Aqueous solution