2013•ElectroanalysisRequires access

A Detailed Study of the (Electro)chemical Behavior of Bis(trifluoromethanesulfonyl)imide Based Ionic Liquids at Different Purification Steps

Daniele Merli, Stefano Protti, Paola Petracca, Maurizio Fagnoni, Antonella Profumo

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Abstract

Abstract A systematic investigation of the major impurities content as well as of their effect on the electrochemical behavior of synthesized N‐butyl‐N‐methylpyrrolidinium (Py1.4), N‐(2‐methoxyethyl)‐N‐methylpyrrolidinium (Py1.102) and 1‐butyl‐3‐methylimidazolium (bmim) bis(trifluoromethanesulfonyl)imide has been carried out and the efficacy of an optimized multistep purification protocol for obtaining ILs suitable for electrochemical applications has been verified.

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Abstract A systematic investigation of the major impurities content as well as of their effect on the electrochemical behavior of synthesized N‐butyl‐N‐methylpyrrolidinium (Py1.4), N‐(2‐methoxyethyl)‐N‐methylpyrrolidinium (Py1.102) and 1‐butyl‐3‐methylimidazolium (bmim) bis(trifluoromethanesulfonyl)imide has been carried out and the efficacy of an optimized multistep purification protocol for obtaining ILs suitable for electrochemical applications has been verified.

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Available abstract

Abstract A systematic investigation of the major impurities content as well as of their effect on the electrochemical behavior of synthesized N‐butyl‐N‐methylpyrrolidinium (Py1.4), N‐(2‐methoxyethyl)‐N‐methylpyrrolidinium (Py1.102) and 1‐butyl‐3‐methylimidazolium (bmim) bis(trifluoromethanesulfonyl)imide has been carried out and the efficacy of an optimized multistep purification protocol for obtaining ILs suitable for electrochemical applications has been verified.

Key concepts: Ionic liquid, Imide, Electrochemistry, Impurity, Materials science, Chemistry, Inorganic chemistry, Combinatorial chemistry

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