1967•Journal of the Chemical Society A Inorganic Physical TheoreticalRequires access

The hydrolysis of some nitroaminecobalt(III) complexes in aqueous solution

S. C. Chan, Puiki Leung

Abstract

The kinetics for the hydrolysis of trinitrodiethylenetriaminecobalt(III) and the tetranitroethylenediaminecobalt(III) anion have been studied at 0° in aqueous solutions containing varying amounts of alkali; the hydrolyses are of the second- and first-order, respectively. Arguments are presented against the conjugate-base mechanism of base hydrolysis of cobaltammine complexes in aqueous solutions.

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Key concepts: Hydrolysis, Aqueous solution, Chemistry, Conjugate, Base (topology), Kinetics, Alkali metal, Ion