Some reactions of soft electrophiles with esters and other compounds containing the thiocarbonyl group
Derek H. R. Barton, Robert V. Stick, Raman Subramanian
Abstract
Derek H. R. Barton, Robert V. Stick, Raman Subramanian
Abstract
The reaction of a number of easily prepared hydroxy-derivatives containing the thiocarbonyl or selenocarbonyl group with soft electrophilic reagents has been studied. The products are derivatives with carbon bonded to the anionic fragment of the electrophile. The reactions occur under mild, neutral conditions and, in appropriate cases, afford good yields.
OpenAlex reports 18 citations for this work. Citation counts describe recorded attention and do not establish research quality.
A contribution statement is not available in the OpenAlex record.
Method details are not available in the OpenAlex metadata.
Findings are not separately available in the OpenAlex metadata.
Limitations are not available in the OpenAlex metadata.
Application details are not available in the OpenAlex metadata.
The reaction of a number of easily prepared hydroxy-derivatives containing the thiocarbonyl or selenocarbonyl group with soft electrophilic reagents has been studied. The products are derivatives with carbon bonded to the anionic fragment of the electrophile. The reactions occur under mild, neutral conditions and, in appropriate cases, afford good yields.
Key concepts: Electrophile, Reagent, Chemistry, Group (periodic table), Organic chemistry, Leaving group, Carbon fibers, Medicinal chemistry