High-Temperature Oxidation of Fe-14Cr-4Al Alloy
Hirobumi Okabe
Abstract
Open-access reader
Hirobumi Okabe
Abstract
Open-access reader
High-temperature oxidations have been performed between 1173 and 1573 K on Fe-14Cr-4Al alloy under isothermal conditions, and also under anisothermal conditions at four linear rates of temperature increase from 1×10-3 to 1.5×10-2 K/s. The activation energy obtained in the anisothermal oxidation with low rates of temperature increase was 282 kJ/mol, in agreement with the isothermal activation energy, 284 kJ/mol. The mass gains under linearly-increasing temperature are calculated using the activation energy and the pre-exponential factor obtained in the isothermal oxidation, and are in accordance with the experimental results obtained at low heating rates.
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High-temperature oxidations have been performed between 1173 and 1573 K on Fe-14Cr-4Al alloy under isothermal conditions, and also under anisothermal conditions at four linear rates of temperature increase from 1×10-3 to 1.5×10-2 K/s. The activation energy obtained in the anisothermal oxidation with low rates of temperature increase was 282 kJ/mol, in agreement with the isothermal activation energy, 284 kJ/mol. The mass gains under linearly-increasing temperature are calculated using the activation energy and the pre-exponential factor obtained in the isothermal oxidation, and are in accordance with the experimental results obtained at low heating rates.
Key concepts: Isothermal process, Activation energy, Alloy, Thermodynamics, Materials science, Chemistry, Analytical Chemistry (journal), Metallurgy