2010•Dalton TransactionsRequires access

Single-crystal to single-crystal transformation of 1D coordination polymervia photochemical [2+2] cycloaddition reaction

Dong Liu, Ni-Ya Li, Jian‐Ping Lang

Abstract

Photochemical single-crystal to single-crystal transformation of one 1D polymer [Cd(bpe)(CBA)(2)](n) afforded a new 1D polymer [Cd(rctt-tpcb)(0.5)(CBA)(2)](n) which underwent hydrothermal reaction in strong acidic solution to form a 3D coordination polymer {[Cd(rtct-tpcb)Cl(2)]·2H(2)O}(n).

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Key concepts: Coordination polymer, Cycloaddition, Single crystal, Hydrothermal circulation, Hydrothermal reaction, Transformation (genetics), Chemistry, Polymer