ChemInform Abstract: Tetrahedral Lewis Base Adducts of an Acyl. Preparation and X‐Ray Structure of the Pyridine Adduct (η5‐C5Me5)Cl3Ta[η2‐ OC(SiMe3)(NC5H5)].
James O. Arnold, T. Don Tilley, Arnold L. Rheingold
Abstract
James O. Arnold, T. Don Tilley, Arnold L. Rheingold
Abstract
Abstract The Ta silaacyl complex (II) reacts with pyridine to give the pyridine 1 :1 adduct (I) which is characterized by 1H NMR and IR spectroscopic data, and X‐ray structural analysis (spacegroup P2′/n, Z=4).
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Abstract The Ta silaacyl complex (II) reacts with pyridine to give the pyridine 1 :1 adduct (I) which is characterized by 1H NMR and IR spectroscopic data, and X‐ray structural analysis (spacegroup P2′/n, Z=4).
Key concepts: Adduct, Pyridine, Chemistry, Lewis acids and bases, Crystallography, X-ray, X-ray crystallography, Base (topology)