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2009•International Journal of Quantum ChemistryRequires access

High‐lying core‐excited quartet states in Li‐like N4+ and F6+ ions

Lin Zhuo, Feng Chen, Bing Cong Gou

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Abstract

Abstract The variational method with mutilconfiguration interaction wave function is used to obtain the energies, fine structures, and hyperfine structures of high‐lying core‐excited quartet states 1s2lnl' 4Po(m) (m = 1–5) and 1s2pnp 4P(m) (m = 1–5) in Li‐like N4+ and F6+ ions, including the mass polarization and relativistic corrections. Restricted variational method is carried out to extrapolate a better energy. The oscillator strengths, lifetime, wavelengths, fine structure, and hyperfine structure for this system are also investigated to compare with other theoretical and experimental data in the literature. © 2009 Wiley Periodicals, Inc. Int J Quantum Chem, 2010

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What this paper is about

Abstract The variational method with mutilconfiguration interaction wave function is used to obtain the energies, fine structures, and hyperfine structures of high‐lying core‐excited quartet states 1s2lnl' 4Po(m) (m = 1–5) and 1s2pnp 4P(m) (m = 1–5) in Li‐like N4+ and F6+ ions, including the mass polarization and relativistic corrections. Restricted variational method is carried out to extrapolate a better energy. The oscillator strengths, lifetime, wavelengths, fine structure, and hyperfine structure for this system are also investigated to compare with other theoretical and experimental data in the literature. © 2009 Wiley Periodicals, Inc. Int J Quantum Chem, 2010

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Available abstract

Abstract The variational method with mutilconfiguration interaction wave function is used to obtain the energies, fine structures, and hyperfine structures of high‐lying core‐excited quartet states 1s2lnl' 4Po(m) (m = 1–5) and 1s2pnp 4P(m) (m = 1–5) in Li‐like N4+ and F6+ ions, including the mass polarization and relativistic corrections. Restricted variational method is carried out to extrapolate a better energy. The oscillator strengths, lifetime, wavelengths, fine structure, and hyperfine structure for this system are also investigated to compare with other theoretical and experimental data in the literature. © 2009 Wiley Periodicals, Inc. Int J Quantum Chem, 2010

Key concepts: Excited state, Hyperfine structure, Atomic physics, Wave function, Ion, Physics, Configuration interaction, Wavelength

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