2009•Zeitschrift für anorganische und allgemeine ChemieRequires access

Synthesis and Description of a Novel Metal‐organic Framework Based on Trigonal Prismatic Building Blocks

Bing Li, Shou‐Tian Zheng, Guo‐Yu Yang

Abstract

Abstract A novel metal‐organic framework based on trigonal prismatic building blocks has been hydrothermally prepared and structurally characterized. It crystallizes in the cubic space group Pa$\bar{3}$ with Z = 8. The oxo‐centered trinuclear complex units are bridged by 1,3‐benzenedicarboxylate (1,3‐BDC) ligands, forming a new 3D open‐framework [Fe3O(H2O)3(1,3‐BDC)3][Cl]·9H2O (1). Its magnetic behavior has been quantitively analyzed by the Bleaney–Bowers equation, indicating the presence of antiferromagnetic interactions within the trinuclear FeIII atoms.

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Key concepts: Trigonal prismatic molecular geometry, Trigonal crystal system, Antiferromagnetism, Crystallography, Metal-organic framework, Metal, Group (periodic table), Materials science