1991•Journal of Applied Polymer ScienceRequires access

Copolymerization of alkyl methacrylates with triallyl cyanurate. Determination of monomer reactivity ratios

Anna Ryttel

Abstract

Abstract The free‐radical copolymerization of propyl, pentyl, hexyl, heptyl, octyl, and dodecyl methacrylates with triallyl cyanurate was investigated. The reactivity ratios were determined using the methods of Fineman‐Ross and Kelen‐Tüdös. The Alfrey‐Price Q and e values for the methacrylates were also evaluated. The effect of the length of alkyl group in methacrylates on reactivity ratios is discussed.

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Key concepts: Reactivity (psychology), Methacrylate, Copolymer, Monomer, Alkyl, Polymer chemistry, Chemistry, Materials science