Electronic Communication in the Formation of a Quartet Molecule 2,6,10-Tris[bis(p-methoxyphenyl)aminium]triphenylene
Takeshi Ibe, Shu Kaiho, Kenichi Oyaizu, Hiroyuki Nishide
Abstract
Takeshi Ibe, Shu Kaiho, Kenichi Oyaizu, Hiroyuki Nishide
Abstract
Abstract A quartet triradical molecule, 2,6,10-tris[bis(p-methoxyphenyl)aminium]triphenylene, was characterized by the electronic interaction among the three aminium sites based on the fused-aromatic, triphenylene-linked, and non-Kekulé connectivity, which lead to the stable high-spin triradical formation.
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Abstract A quartet triradical molecule, 2,6,10-tris[bis(p-methoxyphenyl)aminium]triphenylene, was characterized by the electronic interaction among the three aminium sites based on the fused-aromatic, triphenylene-linked, and non-Kekulé connectivity, which lead to the stable high-spin triradical formation.
Key concepts: Triphenylene, Chemistry, Tris, Molecule, Stereochemistry, Medicinal chemistry, Computational chemistry, Organic chemistry