Metallogenic events and tectonic setting of the Duobaoshan ore field in Heilongjiang Province, NE China

The Duobaoshan ore field, a major center of metal production in Northeast China, is located in the northeast of the Xing’an–Mongolia Orogenic Belt (the eastern part of the Central Asian Orogenic Belt) and within the northern Greater Xing’an Mountains. Several types of ore deposits are mined in the Duobaoshan region, including the Duobaoshan and Tongshan porphyry copper–molybdenum deposits, the Sankuanggou skarn iron–copper deposit, and the Zhengguang epithermal gold deposit. Zircon grains from the Tongshan granodiorite and porphyritic granite yield laser ablation–inductively coupled plasma–mass spectrometry (LA–ICP–MS) U–Pb weighted mean ages of 475.9 ± 0.8 Ma and 230.9 ± 0.9 Ma to 240.7 ± 0.8 Ma, respectively. The Re–Os isochron age of molybdenites from the Tongshan deposit is 473 ± 4 Ma. Because both field observations and petrographic analysis identified disseminated chalcopyrite, pyrite, and malachite in the porphyritic granite, the isotope dating indicates that the Tongshan deposit underwent at least two magmatic–mineralization events, during the Ordovician and the Triassic. Zircon grains from the metallogenic granodiorite of the Sankuanggou skarn deposit yield an age of 176.1 ± 0.3 Ma, and Re–Os dating of molybdenite gives an age of 173 ± 6 Ma, indicating a Jurassic event. Based on previous research and the new geochemical analysis presented in this study, it is inferred that the magmatism and mineralization of the Sankuanggou deposit were associated with the subduction of the Paleo-Pacific Plate. The Duobaoshan region has therefore experienced at least three major magmatic and mineralization events, during the Ordovician (470–480 Ma), the Triassic (230–240 Ma), and the Early Jurassic (170–180 Ma).