Major element composition of stratospheric micrometeorites

Abstract— The elemental compositions of 200 interplanetary dust particles (IDPs) collected in the stratosphere have been determined by energy dispersive X‐ray (EDX) analysis. The results reasonably define the normal compositional range of chondritic interplanetary dust particles averaging 10 micrometers in size, and constitute a database for comparison with individual IDPs, meteorites, and spacecraft data from comets and asteroids. The average elemental composition of all IDPs analyzed is most similar to that of CI chondrites, but the data show that there are small yet discernable differences between mean IDP composition and the CI norm. Individual particles were classified into broad morphological groups, and the two major groups show unambiguous compositional differences. The “porous” group is a close match to bulk CI abundances, but the “smooth” group has systematic Ca and Mg depletions, and contains stoichiometric “excess” oxygen consistent with the presence of hydrous phases. Similar depletions of Ca and Mg in CI and CM matrix have been attributed to leaching, and by analogy we suggest that particles in the smooth group have also been processed by aqueous alteration. The occurrence of carbonates, magnetite framboids, and layer silicates provides additional evidence that at least a significant number of the smooth‐class IDPs have been substantially processed by aqueous activity. The presence or absence of aqueous modification in members of a particle sub‐class is an important clue to the origin. Although it cannot be proven, we hypothesize that extensive aqueous activity only occurs in asteroids and that, accordingly, the smooth class of IDPs has an asteroidal origin. If both comets and asteroids are major sources of interplanetary dust, then by default the porous particles are inferred to be dominated by cometary material.