1982•Journal of the Chemical Society Chemical CommunicationsRequires access

Formation of vanadium antimonate and low temperature stabilisation of β-Sb 2 O 4 by vanadium

Frank J. Berry, Michael E. Brett, William R. Patterson

Abstract

The formation of hitherto disputed monophasic vanadium antimonate is reported and its thermally induced decomposition into β-Sb2 O4 containing ca. 5% vanadium is associated with a new low-temperature stabilisation of this phase; on further heating the hexagonal ‘β-Sb2O4’ plate-type crystals develop crystalline outgrowths of vanadium antimonate.

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Available abstract

Key concepts: Antimonate, Vanadium, Hexagonal crystal system, Chemistry, Decomposition, Phase (matter), Crystallography, Inorganic chemistry