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1978•Helvetica Chimica ActaRequires access

Tricyclo[4.2.2.22,5] dodecane and Tricyclo [4.2.2.12,5]undecane. Preliminary communication

Beat Ernst, Camille Ganter

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Abstract

Abstract A synthesis of tricyclo [4.2.2.22,5]dodecane (19), a novel tricyclic C12H20 compound, is described. The key intermediate ketone 13 was prepared either from the C10‐photodimer 1 of cyclopentadienone or the C11‐cycloaddition products 11 and 12. 13 was also transformed to tricyclo [4.2.2.12,5]undecane (8).

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What this paper is about

Abstract A synthesis of tricyclo [4.2.2.22,5]dodecane (19), a novel tricyclic C12H20 compound, is described. The key intermediate ketone 13 was prepared either from the C10‐photodimer 1 of cyclopentadienone or the C11‐cycloaddition products 11 and 12. 13 was also transformed to tricyclo [4.2.2.12,5]undecane (8).

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Available abstract

Abstract A synthesis of tricyclo [4.2.2.22,5]dodecane (19), a novel tricyclic C12H20 compound, is described. The key intermediate ketone 13 was prepared either from the C10‐photodimer 1 of cyclopentadienone or the C11‐cycloaddition products 11 and 12. 13 was also transformed to tricyclo [4.2.2.12,5]undecane (8).

Key concepts: Undecane, Chemistry, Dodecane, Ketone, Cycloaddition, Stereochemistry, Organic chemistry, Catalysis

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Tricyclo[4.2.2.22,5] dodecane and Tricyclo [4.2.2.12,5]undecane. Preliminary communication — Research Paper | ScholarLens